Date of Award
1977
Document Type
Thesis
Degree Name
Master of Science (M.S.)
Department
Chemistry
First Advisor
Larry O. Spreer
First Committee Member
Michael J. Minch
Second Committee Member
Patrick R. Jones
Abstract
4-bromopyridine hydrochloride is a compound which has a relatively high formal charge on the 4 carbon. Molecular orbital calculations on pyridine show a +0.18 charge on the 4 position, a +0.15 charge on the 2 position, and a +0.05 charge on the 3 position with the nitrogen holding a -0.59 charge.12 And in aqueous acidic solutions, and added +1 charge would be distributed throughout the aromatic ring of the resulting pyridinium ion, thus increasing all charges. Benzene would show all carbons being identical having relative charges of zero each on the scale used for pyridine. As a result of these considerations, an attempt at the formation of pentaaquo-4-pyridylchromium(III) ion ensued. Information in the following sections will show success in this attempt
Pages
67
Recommended Citation
Biggs, Danny Alan. (1977). Synthesis and characterization of Pentaaquo-4-pyridylchromium (III) ion. University of the Pacific, Thesis. https://scholarlycommons.pacific.edu/uop_etds/1924
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