Variable diastereoselectivity in acylation of 2-substituted cyclohexanols
Poster Number
22
Format
Poster Presentation
Faculty Mentor Name
V. Samoshin
Faculty Mentor Department
Chemistry
Abstract/Artist Statement
The ratio of diastereomeric products A and B in acylation of 2-substituted cyclohexanols was found to depend dramatically on the nature of substituents, solvent and additives. Unusual inversion of diastereoselectivity upon change of a solvent or addition of tertiary amines was found for certain combinations of reactants and conditions.
Location
DeRosa University Center, Ballroom
Start Date
21-4-2011 6:00 PM
End Date
21-4-2011 8:00 PM
Variable diastereoselectivity in acylation of 2-substituted cyclohexanols
DeRosa University Center, Ballroom
The ratio of diastereomeric products A and B in acylation of 2-substituted cyclohexanols was found to depend dramatically on the nature of substituents, solvent and additives. Unusual inversion of diastereoselectivity upon change of a solvent or addition of tertiary amines was found for certain combinations of reactants and conditions.