Solution Geometry and Long-Range Coupling in Carbohydrate Mimetics from Glycal Dimerization
Document Type
Poster
Department
Chemistry
Conference Title
239th American Chemical Society (ACS) National Meeting
Organization
American Chemical Society (ACS)
Location
San Francisco, CA
Conference Dates
March 21-25, 2010
Date of Presentation
3-22-2010
Abstract
The solution structures of three carbohydrate mimetics with gluco-, cellobio- and lacto-configurations from glycal dimerization are discussed. NOE experiments were used to establish the conformation across the glycosidic bond for both tetrasaccharide mimetics. J-resolved HMBC NMR experiments were used to measure long-range H,C coupling constants derived from iterative fitting of sin(pJHCt). The structures were found to be rigid with very little conformational averaging across the direct C-C-linkage.
Recommended Citation
Franz, A. H.
(2010).
Solution Geometry and Long-Range Coupling in Carbohydrate Mimetics from Glycal Dimerization.
Paper presented at 239th American Chemical Society (ACS) National Meeting in San Francisco, CA.
https://scholarlycommons.pacific.edu/cop-facpres/383
Comments
Click here to view the Conference Organization's website