Title
Kinetics And Stoichiometry Of The Aquation Reaction Of Pentaaquodihalomethyl Chromium(Iii) Ions
Date of Award
1977
Document Type
Dissertation
Degree Name
Doctor of Philosophy (Ph.D.)
Department
Chemistry
First Advisor
Larry O. Spreer
First Committee Member
Richard P. Dodge
Second Committee Member
Michael J. Minch
Third Committee Member
Patrick R. Jones
Fourth Committee Member
Raymond M. Quick
Abstract
This study was designed to provide information about the mechanisms of pentaaquodihalomethyl chromium(III) ions (halo chloro, bromo and iodo).
...
Mechanisms based on carbonium ion, carbeno and carbenoid type intermediates are proposed. A mechanism based on the nucleophillic attack (SN2) of water on the carbon center leading to a metal-formyl type intermediate is suggested as best fitting all the criteria observed in these studies.
(see PDF file for additional Abstract as it includes formulas)
Pages
147
Recommended Citation
Akhtar, Mohammad Javaid. (1977). Kinetics And Stoichiometry Of The Aquation Reaction Of Pentaaquodihalomethyl Chromium(Iii) Ions. University of the Pacific, Dissertation. https://scholarlycommons.pacific.edu/uop_etds/3386
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