Title

Total Synthesis of Aminomethyl C-glycosides.

Poster Number

15

Format

Poster Presentation

Abstract/Artist Statement

A practical high yield total synthesis protocol was developed, from non-natural achiral starting materials, of partially functionalized N-protected and deprotected, mono- and bicyc!ic aminomethyl tetrahydropyrans, in several configurations. A synthesis of complex homoallylic alcohols from acetals was also developed. Bicyclic tetrahydropyran derivatives, i.e. C-disaccharides, were similarly prepared.

Location

DeRosa University Center

Start Date

1-5-2001 9:00 AM

End Date

1-5-2001 5:00 PM

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May 1st, 9:00 AM May 1st, 5:00 PM

Total Synthesis of Aminomethyl C-glycosides.

DeRosa University Center

A practical high yield total synthesis protocol was developed, from non-natural achiral starting materials, of partially functionalized N-protected and deprotected, mono- and bicyc!ic aminomethyl tetrahydropyrans, in several configurations. A synthesis of complex homoallylic alcohols from acetals was also developed. Bicyclic tetrahydropyran derivatives, i.e. C-disaccharides, were similarly prepared.