Total Synthesis of Aminomethyl C-glycosides.
Poster Number
15
Format
Poster Presentation
Abstract/Artist Statement
A practical high yield total synthesis protocol was developed, from non-natural achiral starting materials, of partially functionalized N-protected and deprotected, mono- and bicyc!ic aminomethyl tetrahydropyrans, in several configurations. A synthesis of complex homoallylic alcohols from acetals was also developed. Bicyclic tetrahydropyran derivatives, i.e. C-disaccharides, were similarly prepared.
Location
DeRosa University Center
Start Date
1-5-2001 9:00 AM
End Date
1-5-2001 5:00 PM
Total Synthesis of Aminomethyl C-glycosides.
DeRosa University Center
A practical high yield total synthesis protocol was developed, from non-natural achiral starting materials, of partially functionalized N-protected and deprotected, mono- and bicyc!ic aminomethyl tetrahydropyrans, in several configurations. A synthesis of complex homoallylic alcohols from acetals was also developed. Bicyclic tetrahydropyran derivatives, i.e. C-disaccharides, were similarly prepared.